Selina Kyle/Catwoman – Batman Returns (1992)

Nothing like a little leather catsuit to draw some attention, right? Selina Kyle as Catwoman (Michelle Pfeiffer) from Batman Returns knows that better than most. After being tossed out of a skyscraper window by her not-so-benevolent boss, Max Shrek (Christopher Walken), Selina turns to her feline companions for inspiration as she takes on Gotham and the Caped Crusader (Michael Keaton) in a little revenge spree. Her feminine feline wiles nearly get the best of the Bat, which is why she makes it onto our list as one of the sexiest supervillains.